Natural refrigerants – balancing ecology and economy perspective
Measures to save energy throughout the life of refrigerating systems are increasingly acquiring significance. In this regard, natural refrigerants offer a double incentive, as they cut back on costs and help protect the environment, postulates Monika Witt.
Measures to save energy throughout the life of refrigerating systems are increasingly acquiring significance. In this regard, natural refrigerants offer a double incentive, as they cut back on costs and help protect the environment, postulates Monika Witt.
The decision as to which refrigerant should be used in a refrigerating or air conditioning system is based on the major criteria of safety, costs and protection of the environment. But against the scenario of constantly increasing energy prices, the energy consumption of a system also plays an increasingly important role. Ideally, the chosen refrigerant should have excellent thermodynamic properties, high chemical stability and good physical characteristics. Furthermore, it should have no or only a negligible impact on the environment, while also being inexpensive and available worldwide.
However, there is no one refrigerant that fulfils all these requirements. And so, in practice, zeroing down on the most suitable refrigerant depends on a series of different factors. Here, the operating area and the operator’s requirements need to be factored in, together with the installation site and environmental aspects. But above all, it is the actual rating of the overall refrigerating system, while taking into account part-load conditions, which has a crucial influence on energy consumption. This is because it is the overall concept of a refrigerating system, which has a greater influence on efficiency than the choice of refrigerant. However, a number of current projects show that systems operating with natural refrigerants are particularly efficient and environment-friendly.
AMMONIA REFRIGERATION SCORES ON ENERGY EFFICIENCY
Ammonia is the refrigerant with demonstrably the best thermodynamic properties. It is the only natural refrigerant which the industry never wanted to dispense with, on account of its high efficiency. Ammonia is also unbeatable in ecological terms: it has no ozone-depletion potential and no global warming potential (ODP and GWP = 0), with a favourable TEWI balance, thanks to the high COP of ammonia systems.
In industrial systems with capacities exceeding 500kW, ammonia is simply unsurpassed in terms of energy and cost efficiency. Also, it is finding increasing use on a smaller scale, for example, in systems with a capacity of less than 500kW, where the quantity of ammonia can be reduced when choosing a suitable secondary refrigerant.
At present, intensive research is in progress in Europe, in particular, in the range of small-capacity systems, with the objective, among others, of developing small, semi-hermetic and hermetic compressors, with output below 100kW. Reduced quantity heat exchangers are also being developed along the same lines. Furthermore, various research projects are also looking at simplified oil management with soluble oils to facilitate DX systems, as well.
Moreover, today, ammonia is also being used increasingly in areas that used to be dominated by synthetic refrigerants. For example, all large exhibition buildings in Germany have been equipped with ammonia liquid chillers for air conditioning. Banks, insurance companies and office buildings, too, increasingly use ammonia liquid chillers for energy-saving air conditioning. Even modern airports make increasing use of ammonia systems, in the light of risk-analysis results, indicating that ammonia does not pose greater hazard potential for the general public or airport employees than systems using synthetic refrigerants.
Ammonia systems, therefore, have been installed not only in Düsseldorf’s refurbished airport, but also in London Heathrow’s new Terminal 5 and in Zurich Airport. The freight hub in New Zealand’s Christchurch Airport also saves energy by using ammonia for cooling systems.
CARBON DIOXIDE – ENERGY EFFICIENT AND ECONOMICAL
The last 10 years have witnessed increase in the interest shown in CO2 refrigerating systems. This is due, for example, to the fact that the global player Nestlé has constantly forged ahead with the development of NH3/CO2 cascade refrigeration plants, demonstrating their energy efficiency, with installations in Europe, United States and Japan. Other companies have followed suit. In addition, this trend has been encouraged by state incentives in some countries.
For instance, the Netherlands grants considerable tax relief for CO2 systems, while taxation on synthetic refrigerants has been increased in Scandinavia. CO2 is also particularly suitable for heat recovery or heat pump systems. Applications of this kind are already widespread in Asia, and other countries can be expected to follow.
How much energy can actually be saved by using CO2 as refrigerant, depends, above all, on the ambient temperature. The efficiency of a CO2 system is clearly superior to a plant operating with synthetic refrigerants when used in the subcritical range. But success is also being achieved in optimising system efficiency even in the supercritical range. This has been confirmed – among others – by the Coca Cola Company, which uses both CO2 and R134a for its 550-litre refrigerators, with the result that the systems operating with CO2 consume 20% to 30% less energy.
In the trans or supercritical mode (temperatures > 31.2°C), CO2 systems are, in principle, less efficient than those using synthetic refrigerants. Even so, when viewed over the whole year, CO2 refrigerating systems are frequently more energy-efficient than those with synthetic refrigerants, as most systems operate in the subcritical range most of the time, particularly in latitudes with moderate weather.
CLIMATE-NEUTRAL COOLING WITH HYDROCARBONS
Hydrocarbons, such as butane, propane and propene are ideal refrigerants. Butane, for example, is very successful in more than 300 million domestic refrigerators currently being used. Furthermore, butane can also be increasingly found in smaller commercial refrigerating systems. The beverages company, Pepsi, for example, compared the efficiency of small drinks chillers with up to 150g coolant and found that units operating with butane consumed up to 27% less energy than those using R134a. Since then, the beverages manufacturer has given preference to butane in these chillers, and it is not the only one. Ben & Jerry used butane for its ice-cream freezers for the first time in the United States, with most satisfactory results.
Propane has very similar thermodynamic properties to R22. Some Asian countries have, therefore, replaced R22 with propane in their central air conditioning systems. They report cutbacks in energy consumption between 10% and 30%, with the systems needing only minimum modifications. Unilever is another company that has recognised the advantages of propane as a refrigerant. During the 2000 Olympic Games in Brisbane and Sydney, the company performed a field study with 360-litre ice-cream freezers, comparing operation with propane to operation with R404A. On an average, the propane freezers permitted energy savings of about nine percent.
Hydrocarbons have excellent thermodynamic properties, which is why refrigerating and air conditioning systems operating with these substances are particularly energy-efficient. They are well miscible with conventional refrigerating oils, and have a relatively high critical temperature. While the flammability of hydrocarbons requires hermetically sealed systems with explosion protection for electrical components, all components are easily available and the current technology copes well with the demands of safe operation. Given the high energy saving potential of systems with hydrocarbons, a number of companies have announced their intentions of operating new refrigerating systems with hydrocarbons.
Up to now, Europe has imposed a 150-gramme filling restriction of hydrocarbons. However, this value was determined arbitrarily, so that it would be preferable to make the filling restriction dependent on the prevailing conditions in each case. Recommendations for such site-dependent limit values could be compiled and developed, for example, in the framework of a scientific research project. Larger filling quantities could probably be permitted if the propane filling is located up high on the roof of a building, or in large, well- ventilated rooms.
In the USA, there seems to be a willingness to rethink the situation. While the use of hydrocarbons hitherto was restricted to industrial applications, this restriction may possibly be lifted in future. For the first time, the US Environmental Protection Agency (EPA), with its highly critical stance on substances that pose a safety risk on account of the product liability laws, has approved of a field study that will test up to 2000 chest freezers operating with flammable refrigerants. This could lead to a real breakthrough.
WATER REFRIGERATION – UP TO 25% POTENTIAL SAVINGS
The evaporation of water has always been used as a means of cooling. But this method that functions quite naturally in the human body through perspiration, presents a challenge when considered on an industrial scale. A huge flow of water vapour is needed to achieve an adequate cooling effect, which in turn, requires the use of turbo-compressors. Suitable machines here consist either of axial compressors with a relatively small base area and many stages, or radial compressors connected in series. However, these are sensitive to load fluctuations and need the operation to be as constant as possible. The situation is further complicated by the fact that the operation takes place in a deep vacuum, which requires a system that is absolutely tight. Even so, these stringent technical requirements are offset by huge energy-saving potential of about 25%, compared to the currently available R134a liquid chilling units. This is why research is in progress in France and in Dresden, Germany, on prototypes for both radial and axial compressors.
AIR – RAPID REFRIGERATION AT LOW ENERGY COSTS
Air is interesting as a refrigerant for temperatures below -50°C. Systems with a closed air circuit are convincing, above all, on account of their particularly rapid cooling at low energy costs. But air has not become widely accepted as a refrigerant because of the comparatively high costs for the overall system. To achieve the necessary mass flow density, expensive turbo-compressor/expander systems are necessary, together with special shaft seals to minimise leakage. However, at the same time, air-cooled systems are also very compact. This is why, at present, they are primarily used for gas liquefaction on tankers, where the high costs are justified in view of the confined space available.
BALANCING THE ENVIRONMENT AND THE BALANCE SHEETS
Natural refrigerants are inexpensive, available in abundance, and can cover nearly every refrigeration application presently in use. Furthermore, they have a very low global warming potential (GWP) compared to synthetic refrigerants. This alone is reason enough to recommend their use. However, it is just as important to make sure that they are highly energy-efficient. After all, more than 80% of the global warming potential posed by refrigerating and air conditioning systems results from system energy consumption and not from refrigerant leaks. At present, around 15% of global electricity consumption is used to generate refrigeration, resulting in huge savings potential. Measures to save energy throughout the entire service life of refrigerating systems are, therefore, acquiring increasing significance, and can help considerably in relieving the burden on the environment. This is where the use of natural refrigerants comes into play, as they offer a double incentive for companies – by reducing energy consumption, they not only cut back on costs, but also help protect the environment. Everything, therefore, points towards the use of natural refrigerants in both ecological and economical terms, in order to safeguard both capital expenditure and the environment in the long run.
| ANNEX |
| Ammonia (NH3)
Ammonia has been successfully used as a refrigerant in industrial refrigeration plants for over 100 years. It is a colourless gas, liquefies under pressure, and has a pungent odour. In coolant technology, ammonia is known as R 717 (R = Refrigerant) and is synthetically produced for use in refrigeration. Ammonia has no ozone depletion potential (ODP = 0) and no direct global warming potential (GWP = 0). Thanks to its high energy efficiency, its contribution to the indirect global warming potential is also low. Ammonia is flammable. However, its ignition energy is 50 times higher than that of natural gas, and it will not burn without a supporting flame. Due to the high affinity of ammonia for atmospheric humidity, it is rated as “hardly flammable”. Ammonia is toxic, but has a characteristic sharp smell, which, when present in air, gives a warning below concentrations of 3 mg/m³. This means that ammonia is evident at levels far below those which endanger health (>1,750 mg/m³). Furthermore, ammonia is lighter than air, and therefore, rises quickly. Carbon dioxide (CO2) Carbon dioxide is known in refrigeration technology as R 744. It has a long history extending back to the mid 19th century. It is a colourless gas that liquefies under pressure, with a slightly acidic odour and taste. Carbon dioxide has no ozone depletion potential (ODP = 0) and negligible direct global warming potential (GWP = 1) when used as a refrigerant in closed cycles. It is non-flammable, chemically inert and heavier than air. It has a narcotic and asphyxiating effect only in high concentrations. Carbon dioxide occurs in nature in abundance. Hydrocarbons Refrigeration plants using hydrocarbons, such as, propane (R 290, C3H8), propene (R 1270, C3H6) or isobutane (R 600a, C4H10) have been in operation all over the world for many years. Hydrocarbons are colourless and nearly odourless gases that liquefy under pressure, and have neither ozone depletion potential (ODP = 0) nor significant direct global warming potential (GWP = 3). Thanks to their outstanding thermodynamic characteristics, hydrocarbons make particularly good energy-efficient refrigerants. They are flammable. However, with currently available safety devices, refrigerant losses are near zero. Hydrocarbons are available at low cost all over the world. Thanks to their ideal refrigerant characteristics, they are commonly used in small plants with low refrigerant charges. |
The writer is the chairperson of Eurammon, the European initiative for natural refrigerants. recruitment

By the time we started the LEED certification programme for the OMD building at Dubai Media City, we had already delivered two LEED-certified projects at TECOM, and the LEED Gold Metito HQ complex (in 2007). We had, therefore, grown in confidence and, perhaps prematurely, thought that we should be able to deliver LEED Gold projects incessantly. But surprises were in store, and at the end of the LEED certification of the OMD project, for the first time in my career, I was able to empathise with Sir Isaac Newton’s humility, when he stated, “I do not know what I may appear to the world, but to myself, I seem to have been only like a boy playing on the seashore, and diverting myself in now and then, finding a smoother pebble or a prettier shell than ordinary, whilst the great ocean of truth lay all undiscovered before me.”

Here, it must be stated that the project’s water savings performance has been benchmarked against both US EPA standards as well as local practices (See Figure 4).
The project has achieved a 100% savings in potable water requirement for landscaping through a two-pronged approach. The irrigation water requirement has been minimised by utilising native plants with low water consuming properties. For the first time in a TECOM project, the AC condensate from the building’s HVAC system has been connected to the irrigation tank located in the basement (See figures 5a and 5b).
Improved insulation for walls and glass
The intention of this credit is to “provide optimal indoor air quality to tenants” (Source: USGBC). This is another LEED segment where the project performed very well, scoring eight points out of a possible 11 points. The facility is designed to enjoy 30% more fresh air, compared to ANSI/ASHRAE 62.1-2004: Ventilation for Acceptable Indoor Air Quality standard requirements, making the building very healthy for its occupants. Also, the HVAC system design complies with ANSI/ ASHRAE 55-2004: Thermal Environmental Conditions for Human Occupancy standard, and thus, provides a comfortable thermal environment for the building occupants.
At this juncture, it is important to share the financial cost-benefit of LEED projects, in order to dispel the popular myth about green buildings costing more. In fact, after the energy- modelling challenges, this was the second key lesson learnt from this project – if an organisation can make green design mainstream, then the concept of green premium does not arise, subject to the level of certification desired. It is interesting to note that, on this project, it was a struggle to identify the additional cost for going green. In fact, other than the administrative costs for the certification and fees paid for the energy modelling, the project did not incur any additional financial burden to achieve the LEED certification.
EPILOGUE
The growing number of certified green projects clearly removes any ambiguity about whether or not external rating systems work in this region. Of the 13 certified projects in the GCC, three are LEED Platinum, six LEED Gold, three LEED Silver and one LEED certified. A majority of the projects being LEED Gold or above, clearly demonstrates that LEED not only works in this region, but actually works quite well. TECOM Investments, through (SEED), is committed to creating a sustainable development industry in the region. As an offshoot of this, the dissemination of technical and financial information from its projects is helping create local case studies – so vitally important for green building practitioners.
Fire hazards within buildings are still a global concern, especially in the UAE, where more than 2,000 fires occur annually. The fires are caused essentially by accidental human factors (60%) and technical failures (40%). They result in deaths, injuries and/or damages, which form a threat to residents and tourists in the UAE. For this reason, preventive safety against fire hazards and disasters has become a major strategic objective in the Dubai Civil Defence Strategic Plan 2009-2015.
If sustainability can be considered as a positive trend taking shape slowly in the UAE to promote efficient green buildings (via effective water and waste management, energy consumption ratings and indoor environmental quality), quality and safety need to be further prioritised by the different construction bodies in the UAE. The quality and safety standards of building construction are still quite low in the UAE. This is due to various factors, such as cost reduction, lack of regulations, minimum specification requirements by consultants, poor labour skills, and disregard towards specifications by actual contractors. As a direct result, the UAE has faced structural collapses affecting some buildings or car parks under construction. But if these collapses constitute tangible and visible proof of bad quality of structural construction, a low level of quality and safety is also affecting the thermal insulation, the HVAC systems, and, indeed, the fire-protection systems, which are really critical, in the event of a fire.
A fire can also cause damage to the environment, given the large amount of combustion gases emitted into the atmosphere during a blaze.
An efficient compartmentalisation is fundamental to ensure a minimum level of safety inside a building. The main objective is to subdivide a building into fire compartments to isolate a fire as soon as it starts and to limit the spread of flames, smoke and heat throughout the existing AC ductwork.
Curtain fire dampers should be replaced by the more efficient fire dampers, described above, in new building, and especially in sensitive buildings – for example, high-rise buildings, hotels, schools, hospitals, which have occupancy, accompanied by potential sleeping risks.
Companies engaged in refrigerated transport may not have been adversely affected by the recent economic downturn but many challenges remain for the sector to contend with. And it’s about time it did something to remedy the situation, as the cold-chain involves more than just transporting foodstuff from field to fork.

Well-implemented supply-chain applications provide significant benefits to all organisations involved with increased visibility, tracking and traceability. In the case of cold-chain applications, the ambient parameters are also to be monitored and are important. The emphasis on this issue stems from the social, economic and environmental impact it can have.
The use of refrigeration systems is almost indispensable when it comes to several activities in modern society. Such systems are responsible for everything from providing thermal comfort in office buildings to maintaining low temperatures (-25ºC to 0ºC) in refrigerated chambers, so that food products are preserved. For such systems, one of the main components is the compressor.
At this juncture, it is important to understand the failures, which can be classified into three types:
Mechartés Researchers conducted CFD analysis of the Columbia College auditorium, in Chicago, Illinois, with the objective of optimising the mechanical cooling system in a spacious area. The auditorium is used for filmmaking and animation. So, apart from heat seepage through the walls and also due to human involvement, it had 50 big light fixtures of 5,000 watts, which contributed to extra heat gain of 250KW.

Prashanth Ojha has a Masters degree in CFD from the Moscow State University and B Tech from NIT, India. He is a Design and Analysis Engineer at Mechartes Researchers. He can be contacted at prashant@mechartes.com
Srihari is a Diploma holder in CFD with a Bachelors degree in Mechanical Engineering from Anna University, Chennai, India. He is a CFD Engineer at Mechartes Researchers. He can be contacted at Srihari@mechartes.com
Saying that they provide high quality, wireless measurement of humidity, temperature and CO2, E+E Elektronik has introduced wireless data transmission, Wireless sensor EE240.